Zuckerman, Norman - Inorganic Reactions and Methods, Vol. 6 (Wiley, 1998) [682p].pdf
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Inorganic Reactions
and Methods
Volume
6
Inorganic Reactions
and Methods
Editor
Arlan D. Norman
Department of Chemistry
University of Colorado
Boulder, CO 80309-021
5
Editorial Advisory Board
Professor N. Bartlett
Department
of
Chemistry
University of California at Berkeley
Berkeley, California 94720
Professor F.A. Cotton
Department of Chemistry
Texas A&M University
College Station, Texas 77840
Professor E.O. Fischer
Anorganisch-chemisches Laboratorium
Professor A.G. MacDiarmid
Department of Chemistry
University of Pennsylvania
Philadelphia, Pennsylvania 19174
Professor M. Schmidt
lnstitut fur Anorganische Chemie der
Universitat
D-8700 Wurzburg
Am Hubland
Germany
der Technischen Universitat
0-8046 Garching
Lichtenbergestrasse 4
Germany
Professor P. Hagenmuller
Laboratoire de Chemie du Solide du
C.N.R.S.
351 cours de la Liberation
F-33405 Talence
France
Professor M.F. Lappert
The Chemical Laboratory
University of Sussex
Falmer, Brighton, BN1 9QJ
England
Professor H. Taube
Department of Chemistry
Stanford University
Stanford, California 94305
Professor L.M. Venanzi
Laboratorium fur Anorganische Chemie
der ETH
CH-80006 Zurich
Universitatsstrasse 5
Switzerland
0
1998 Wiley-VCH, Inc.
Inorganic Reactions
and Methods
Volume
6
Formation
of
Bonds
to
0,
S, Se, Te,
Po (Part
2)
Founding Editor
J. J. Zuckerman
Editor
A. D.
Norman
@3
W
I LEY-VCH
New York Chichester
-
Weinheim
-
Brisbane
-
Singapore
*
Toronto
This book is printed on acid-free paper.
@
Copyright
0
1998 by Wiley-VCH, Inc. All rights reserved
Published simultaneously in Canada.
No part of this publication may be reproduced, stored in a retrieval system or transmitted in any
form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise,
except as permitted under Sections 107 or 108 of the 1976 United States Copyright Act, without
either the prior written permission of the Publisher, or authorization through payment of the
appropriate per-copy fee
to
the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA
01923, (978) 750-8400, fax (978) 750-4744. Requests
to
the Publisher for permission should be
addressed to the Permissions Department, John Wiley
i3
Sons, Inc.,605 Third Avenue, New York,
NY 10158-0012, (212) 850-6011, fax (212) 850-6008, E-Mail: PERMREQ@WILEY.COM.
Library of Congress Catalog Card Number: 85-15627
ISBN 0-471-24677-8
10 9 8 7 6 5
4
3 2 1
Contents of Volume
6
xvii
xxiii
xxvii
xxix
How
to
use this Book
Preface to the Series
Editorial Consultants to the Series
Contributors
to
Volume
6
3.7
Formation
of
the Group
VIB
(0,
S,
Se, Te,
Po)-
Group
IB
(Cu, Ag, Au)
or IIB
(Zn,
Cd,
Hg)
Metal Bond
1
Introduction
Formation of the Oxygen-Group IB or IIB Bond
From Dioxygen and Ozone
By Reaction with the Metal
By Addition
to
Low-Valent and Unsaturated
3.7.1
3.7.2
3.7.2.1
3.7.2.1.1
3.7.2.1.2
Metal Complexes
By Insertion into Metal-Ligand Bonds
3.7.2.1.3
3.7.2.2
3.7.2.2.1
3.7.2.2.2
From Water and Alcohols
By Reaction with Elements
By Hydrolysis or Alcoholysis
of
Metal-Ligand Bonds
4
3.7.2.3
From Hydrogen Peroxide and Organic
Peroxides
By Oxidation of the Metals and Their
6
3.7.2.3.1
6
Complexes
3.7.2.3.2
By Oxidation
of
the Ligands Coordinated
to
the Metals
7
From Neutral Oxygen Donor Ligands [Ethers,
Aldehydes, Ketones, Pyridine N-Oxides,
Phosphine Oxides, Arsine Oxides and
Dialkyl(ary1) Sulfoxides]
By Ligand Displacement Reactions with
3.7.2.4
7
3.7.2.4.1
7
a
Transition Metal Complexes
3.7.2.4.2
3.7.2.5
By Insertion into the Metal-Ligand Bonds
From Bidentate and Polydentate Oxygen
Donor Ligands (from Polyethers and
Crown Ethers, Macrocycles,
2,4-Pentanedione, etc.)
9
V
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